27 July 2023
We are happy to inform you that a new article has just been published on Membranes journal. The article is entitled “Permselectivity and Ionic Conductivity Study of Na+ and Br− Ions in Graphene Oxide-Based Membranes for Redox Flow Batteries” and it has been written by Bar Ilan University with Politecnico di Torino and IIT (Italian Institute of Technology).
We put below a short abstract of the article:
Permselectivity of a membrane is central for the development of electrochemical energy storage devices with two redox couples, such as redox flow batteries (RFBs). In RFBs, Br3−/Br− couple is often used as a catholyte which can cross over to the anolyte, limiting the battery’s lifetime. Naturally, the development of permselective membranes is essential to the success of RFBs since state-of-the-art perfluorosulfonic acid (PFSA) is too costly. This study investigates membranes of graphene oxide (GO), polyvinylpyrrolidone (PVP), and imidazole (Im) as binder and linker, respectively. The GO membranes are compared to a standard PFSA membrane in terms of ionic conductivity (Na+) and permselectivity (exclusion of Br−). The ionic conduction is evaluated from electrochemical impedance spectroscopy and the permselectivity from two-compartment diffusion cells in a four-electrode system. Our findings suggest that the GO membranes reach conductivity and permselectivity comparable with standard PFSA membranes.
We would like to thank our partner, Andrea Lamberti, from Politecnico di Torino for this great achievement!